Structural Aspects of Monomeric Platinum Coordination Complexes
نویسندگان
چکیده
منابع مشابه
synthesis of binuclear platinum complexes containing biphosphine ligand
هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
Systematic structural control of multichromic platinum(II)-diimine complexes ranging from ionic solid to coordination polymer.
Reactions of a Pt(II)-diimine-based metalloligand Na(2)[Pt(CN)(2)(4,4'-dcbpy)] (4,4'-H(2)dcbpy = 4,4'-dicarboxy-2,2'-bipyridine) with alkaline-earth metal salts Mg(NO(3))(2)·6H(2)O, CaCl(2), SrCl(2)·6H(2)O, and BaBr(2)·2H(2)O in aqueous solution gave luminescent complexes formulated as [Mg(H(2)O)(5)][Pt(CN)(2)(4,4'-dcbpy)]·4H(2)O (MgPt-4·9H(2)O), {[Ca(H(2)O)(3)][Pt(CN)(2)(4,4'-dcbpy)]·3H(2)O}(∞...
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Invited for this month's cover picture are the groups of Prof. Alfonso Polo and Dr. Albert Poater at the Universitat de Girona, as well as their collaborators from the Universitat Autònoma de Barcelona and the Institute of Chemical Research of Catalonia. The cover picture shows phosphanylthiolate ligand coordination on a platinum(II) center to give only the bischelate cis -P,P isomer when the l...
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Platinum(II) complexes bearing various alkyne-pyrene, alkyne-4'-terpyridine and alkyne-dibutoxyphenylacetylide-terpyridine units were constructed in a step-by-step procedure based on copper-promoted cross-coupling reactions with preconstructed modules; formation of bis(ligand) complexes of Fe(II) and Zn(II) by binding of the pendent terpyridine units provided heterotrinuclear derivatives, all o...
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ژورنال
عنوان ژورنال: Materials Sciences and Applications
سال: 2014
ISSN: 2153-117X,2153-1188
DOI: 10.4236/msa.2014.58056